Crude
oils from different locations on earth all started from a common
source in the organisms, but with differing temperature- pressure
and geologic histories. Gross patterns have always been obvious
in crude (crudes with lower SpGr have more light components), etc,
but detailed relationships have been difficult to see.
The
use of only "whole crude" properties (density, sulfur,
ConCarbon, metals, etc) would not at first seem likely to give good
predictions of cut yields and properties. However, HPI has employed
a number of techniques which make this possible. First, yields and
whole crude properties are corrected to a C6+ basis, which eliminates
a major (often man-made) impact on crude characteristics, i.e. varying
stabilization levels. The Assay Simulator requires the user to enter
the light ends yields (pentane and lighter) so that the yields and
properties can be corrected for stabilization levels. Secondly,
the World models use the overall K factor to characterize the crude.
While this is not a measured property, it can be determined from
a Base crude. Furthermore, K factor tuning
corrections are determined for each cut and each property of the
Base assay, to further refine the model.
The
CCPP models capture two independent aspects of assay cut
properties: 1) the effect of cut points, and 2) the effect of Whole
Crude (WC) properties. Accuracy statistics
from the prediction process show that WC properties often relate
well to the cut properties, and small tuning ajustments can be made
to an get exact to the Base assay. However, some properties do not
show a good relationship to the WC properties, so an offset is determined
to exactlt match the Base assay.
The
CCPP TBP yield predictions have been shown to be generally
more accurate than Simulated Distillations done by multiple laboratories.
The SimDist can be a better process for estimating yields (especially
for blends of very light and very heavy crudes), but requires diligence
in the laboratories. In additon, corrections should be generated
between known Still Distillations and corresponding SimDists. This
is a complicated process that most assay users are not likely to
perform. Even if the SimDist is used for estimating the TBP curve,
the Assay Simulator may be useful for predicting other cut properties.
There
are obvious limitations to this approach of using whole crude properties.
One problem is the increasing use of synthetic crudes, the properties
of which are so different from natural oils that blends with them
will not necessarily correlate to whole crude properties. While
blending of crudes can sometimes cause confusion, if the crudes
are from the same region they should predict quite well if the blend
did not create a "dumbell" crude (a very light with a
very heavy). While many properties predict quite well, the predictions
of the lighter cuts for sulfur and nitrogen are less accurate. The
tuning factors for these properties are larger in magnitude.
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